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题名: Networks with hexagonal circuits in co-ordination polymers of metal ions (Zn-II, Cd-II) with 1,1 '-(1,4-butanediyl)bis(imidazole)
作者: Ma JF ; Liu JF ; Xing Y ; Jia HQ ; Lin YH
刊名: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
出版日期: 2000
期号: 14, 页码:2403-2407
关键词: COORDINATION POLYMERS ; STRUCTURAL CHARACTERIZATION ; 2-DIMENSIONAL POLYROTAXANE ; SILVER(I) CATIONS ; MOLECULAR LADDERS ; COMPLEXES ; PYRAZINE ; SHEETS ; 1,4-BIS(IMIDAZOL-1-YLMETHYL)BENZENE ; INTERPENETRATION
通讯作者: Ma JF
中文摘要: Three new compounds, [ZnL1.5(H2O)(SO4)]. 6H(2)O 1, [ZnL1.5(H2O)(2)][NO3](2). 2H(2)O 2 and [CdL1.5(H2O)(2)(SO4)]. 4H(2)O 3 were obtained from self-assembly of the corresponding metal salts with 1,1'-(1,4-butanediyl)bis(imidazole) (L). In both 1 and 2 zinc ion is five-co-ordinated, showing a less-common trigonal bipyramidal co-ordination polyhedron, while cadmium ion of 3 is six-co-ordinated with a common octahedral arrangement. The sulfate ions of 1 and 3 are co-ordinated, however the nitrate ions of 2 are not. Each of the three compounds is composed of a (6, 3) network with the hexagonal smallest circuit containing six metal ions and six L; each L is co-ordinated to two metal ions, acting as a bridging ligand. In 1 the 2-D sheet of (6, 3) networks is interpenetrated in an inclined mode by symmetry related, identical sheets to give an interlocked 3-D structure, while the (6, 3) networks of both 2 and 3 stack in a parallel fashion to construct frameworks having channels.
收录类别: SCI收录期刊论文
语种: 英语
WOS记录号: WOS:000088758800025
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.ciac.jl.cn/handle/322003/19639
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Ma JF;Liu JF;Xing Y;Jia HQ;Lin YH.Networks with hexagonal circuits in co-ordination polymers of metal ions (Zn-II, Cd-II) with 1,1 '-(1,4-butanediyl)bis(imidazole),JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS,2000,(14):2403-2407
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